1,2-Dichloro-4-nitrobenzene → HCID 67096045, compound

HRID 2075994Notes

Reaction equation

HRID 2075994 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]([N+:9]([O-:11])=[O:10])[CH:5]=[CH:6][C:7]=1Cl.[CH3:12][C:13]1[N:14]=[CH:15][NH:16][CH:17]=1>C(OCC)(=O)C>[Cl:1][C:2]1[CH:3]=[C:4]([N+:9]([O-:11])=[O:10])[CH:5]=[CH:6][C:7]=1[N:16]1[CH:17]=[C:13]([CH3:12])[N:14]=[CH:15]1

Participants

4

Reactant 2

HCID 74431,2-Dichloro-4-nitrobenzeneHCID 178418800HCID 178418800, compound

Product 1

HCID 67096045HCID 67096045, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

The title compound was prepared from 3,4-dichloronitrobenzene and 4-methylimidazole using in analogous manner the procedure described in example 4a). Chromatography on silica gel using ethyl acetate as eluent gave the title compound as a slightly greenish solid in 64% yield. MS ISP (m/e): 238.0/240.2 (100/40) [(M+H)+].

Sources & evidence

ORD record
ord-9979e9501f4e47cf8703b0d0625501c0
Source dataset
uspto-grants-2011_04
Patent number
US07923450B2

Reaction notes

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