HuagongsheHuagongshe Chemistry Print Report · For research reference only
tert-Butoxy bis(dimethylamino)methane → Ethyl 3-[1-dimethylamino-methylidene]-2-oxo-cyclohexanecarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | tert-Butoxy bis(dimethylamino)methane | HCID 79885 | — |
| Reactant | Ethyl 2-oxocyclohexanecarboxylate | HCID 95543 | — |
| Product | Ethyl 3-[1-dimethylamino-methylidene]-2-oxo-cyclohexanecarboxylate | HCID 67096118 | — |
Reaction Steps
Ethyl 2-oxo-cyclohexanecarboxylate (38 mg, 0.22 mmol) was reacted with tert.-butoxy-bis-(dimethylamino)-methane using in analogous manner the procedure described in example 45a) to give crude title compound (49 mg) as a yellow oil which was used directly in the next step. MS ISP (m/e): 226.1 [(M+H)+].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07923450B2 |
| Source dataset | uspto-grants-2011_04 |
| ORD ID | ord-25f8234a8d644ff2a1f01d8c715b06d8 |
| Source note | uspto-grants-2011_04 |