HuagongsheHuagongshe Chemistry Print Report · For research reference only
(4-Bromo-2-nitrophenyl)methanol → 4-Bromo-2-nitrobenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (4-Bromo-2-nitrophenyl)methanol | HCID 15906236 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 4-Bromo-2-nitrobenzaldehyde | HCID 608099 | 78% |
Reaction Steps
Manganese (IV) oxide (4 eq) was added to a 0.18M solution of (4-bromo-2-nitrophenyl)methanol in dichloromethane. The suspension was stirred at ambient temperature under Argon for 12 h. The reaction mixture was filtered through celite and filter cake was washed with dichloromethane. The combined filtrate was concentrated to give brown color solid in 78% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07932262B2 |
| Source dataset | uspto-grants-2011_04 |
| ORD ID | ord-c35dc245435644239b390d654b968345 |
| Source note | uspto-grants-2011_04 |