HRID2079891

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID2734326

4-Cyanophenylboronic acid

C7H6BNO2

结构：CC(C)n1cc(-c2ccc(C#N)cc2)c2ccc([N+](=O)[O-])cc21

HCID57442194

未命名化合物

结构：O=[N+]([O-])c1ccc2c(Br)cn(S(=O)(=O)c3ccccc3)c2c1

HCID57442196

未命名化合物

PRODUCTS

生成物

结构：N#Cc1ccc(-c2cn(S(=O)(=O)c3ccccc3)c3cc([N+](=O)[O-])ccc23)cc1

HCID57442242

未命名化合物

PROCEDURE

实验过程

Prepare this compound from 1-benzenesulfonyl-3-bromo-6-nitro-1H-indole, 7, and 4-cyanophenylboronic acid using Method C described above for 4-(1-isopropyl-6-nitro-1H-indol-3-yl)-benzonitrile 5. Purify by precipitation from EtOAc/hexanes. 1H NMR (DMSO-d6) δ 8.78 (d, 1H, J=1.8 Hz), 8.73 (s, 1H), 8.17 (dd, 1H, J=2.2, 8.8 Hz), 8.14-8.11 (m, 2H), 8.07 (d, 1H, J=8.8 Hz), 7.97-7.92 (m, 4H), 7.72 (tt, 1H, J=1.3, 7.5 Hz), 7.63-7.59 (m, 2H).

WORKUP

后处理

customPurify by precipitation from EtOAc/hexanes