Ethanol → HCID 54097978, compound

HRID 2081886Notes

Reaction equation

[C:1]([O:21][CH:22]1[CH2:27][CH2:26][N:25]([OH:28])[CH2:24][CH2:23]1)(=[O:20])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]([O:12][CH:13]1[CH2:18][CH2:17][N:16]([OH:19])[CH2:15][CH2:14]1)=[O:11].[C:29](=O)([O-])[O-].[K+].[K+].[CH2:35](Br)[CH:36]=[CH2:37].[CH2:39](O)[CH3:40]>>[C:1]([O:21][CH:22]1[CH2:23][CH2:24][N:25]([O:28][CH2:29][CH:39]=[CH2:40])[CH2:26][CH2:27]1)(=[O:20])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]([O:12][CH:13]1[CH2:14][CH2:15][N:16]([O:19][CH2:35][CH:36]=[CH2:37])[CH2:17][CH2:18]1)=[O:11]

Participants

Reactant 4

HCID 702Ethanol

HCID 7841Allyl bromide

HCID 11430Potassium Carbonate

HCID 54264533HCID 54264533, compound

Product 1

HCID 54097978HCID 54097978, compound

Procedure

Following the general procedure of Example 1 using bis(1-hydroxypiperidin-4-yl) sebacate, potassium carbonate and allyl bromide in ethanol solvent, the title compound is obtained.

Sources & evidence

ORD record: ord-c6afeefd83a348c4865bc9aa85801995
Source dataset: uspto-grants-1993_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05185448

Reaction notes

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