HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hexamethyldisilazane → HCID 15116548, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hexamethyldisilazane | HCID 13838 | — |
| Reactant | Trimethylsilane | HCID 70435 | — |
| Reactant | Perhydroazonine | HCID 79742 | — |
| Reactant | Ammonium Sulfate | HCID 6097028 | — |
| Product | Perhydroazonine | HCID 79742 | — |
| Product | HCID 15116548 | HCID 15116548 | 165.5% |
Reaction Steps
The silylamine of octahydroazonin is prepared by combining octahydroazonin (12.7 g, 0.1 moles) and trimethylsilane (0.12 moles) and 0.5 moles hexamethyldisilazane +150 mg of ammonium sulfate. The mixture is refluxed for 90 hr and distilled under vacuum to yield 16.5 g of 1-trimethylsilyl octahydroazonin (82%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05188897 |
| Source dataset | uspto-grants-1993_02 |
| ORD ID | ord-276d17aff1bb44deb0181f94242a8bc7 |
| Source note | uspto-grants-1993_02 |