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HRID2082278

反应详情

EQUATION

反应方程式

HRID 2082278 的结构方程式

REACTANTS

反应物

4
结构：C[Si](C)(C)N[Si](C)(C)C
HCID13838

Hexamethyldisilazane

C6H19NSi2

结构：C[SiH](C)C
HCID70435

Silane, trimethyl-

C3H10Si

结构：C1CCCCNCCC1
HCID79742

Perhydroazonine

C8H17N

结构：O=S(=O)([O-])[O-].[NH4+].[NH4+]
HCID6097028

Ammonium sulfate

H8N2O4S

PRODUCTS

生成物

2
结构：C1CCCCNCCC1
HCID79742

Perhydroazonine

C8H17N

结构：C[Si](C)(C)N1CCCCCCCC1
HCID15116548

未命名化合物

收率 165.5%

PROCEDURE

实验过程

The silylamine of octahydroazonin is prepared by combining octahydroazonin (12.7 g, 0.1 moles) and trimethylsilane (0.12 moles) and 0.5 moles hexamethyldisilazane +150 mg of ammonium sulfate. The mixture is refluxed for 90 hr and distilled under vacuum to yield 16.5 g of 1-trimethylsilyl octahydroazonin (82%).

WORKUP

后处理

  1. temperatureThe mixture is refluxed for 90 hr
  2. distillationdistilled under vacuum