Hydrogen Peroxide → HCID 3345049, compound

HRID 2082331Notes

Reaction equation

HRID 2082331 reaction equation
[OH:1]O.[N+:3]([C:6]1[CH:7]=[C:8]([C:12]2[CH:17]=[CH:16][N:15]=[CH:14][CH:13]=2)[CH:9]=[CH:10][CH:11]=1)([O-:5])=[O:4]>C(O)(=O)C>[N+:3]([C:6]1[CH:7]=[C:8]([C:12]2[CH:17]=[CH:16][N+:15]([O-:1])=[CH:14][CH:13]=2)[CH:9]=[CH:10][CH:11]=1)([O-:5])=[O:4]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 4595574-(3-nitrophenyl)pyridine

Product 1

HCID 3345049HCID 3345049, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Conditions

Temperature
70 °C

Procedure

Aqueous hydrogen peroxide (27.5 wt. %, 6.4 ml) was added to a solution of 4-(3-nitrophenyl)pyridine (5 g) in glacial acetic acid (50 ml), and the mixture was heated to approx 70° C. overnight. The mixture was then evaporated and the residue was triturated with ether. The product (6 g), still containing some acetic acid, was used without further purification. Mp 193°-196° C.

Workup

  1. customThe mixture was then evaporated
  2. customthe residue was triturated with ether
  3. additionThe product (6 g), still containing some acetic acid
  4. customwas used without further purification

Sources & evidence

ORD record
ord-cd25da15ab9d47c8a4dce8614f98a084
Source dataset
uspto-grants-1993_02
Patent number
US05189047

Reaction notes

Loading…