[2,6-Dichloro-4-(trifluoromethyl)phenyl]hydrazine → HCID 136341206, compound

HRID 2082380Notes

Reaction equation

HRID 2082380 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([C:8]([F:11])([F:10])[F:9])[CH:5]=[C:4]([Cl:12])[C:3]=1[NH:13][NH2:14].O=[C:16]([CH:20]=[N:21][OH:22])[CH:17]=[N:18][OH:19]>C(O)C>[Cl:1][C:2]1[CH:7]=[C:6]([C:8]([F:9])([F:11])[F:10])[CH:5]=[C:4]([Cl:12])[C:3]=1[NH:13][N:14]=[C:16]([CH:20]=[N:21][OH:22])[CH:17]=[N:18][OH:19]

Participants

4

Reactant 2

HCID 688223[2,6-Dichloro-4-(trifluoromethyl)phenyl]hydrazineHCID 6399789Propanedial, 2-oxo-, 1,3-dioxime

Product 1

HCID 136341206HCID 136341206, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 2,6-dichloro-4-trifluoromethylphenylhydrazine (34 g), 2-oxopropanedial 1,3-dioxime (17 g) and ethanol (300 ml) was heated under reflux for 31/2 hours. The solvent was evaporated under reduced pressure and the residue triturated with light petroleum (bp 40°-60°) and filtered to give 2-oxopropanedial 2-(2,6-dichloro-4-trifluoromethylphenylhydrazone) 1,3-dioxime.

Workup

  1. temperaturewas heated
  2. temperatureunder reflux for 31/2 hours
  3. customThe solvent was evaporated under reduced pressure
  4. customthe residue triturated with light petroleum (bp 40°-60°)
  5. filtrationfiltered

Sources & evidence

ORD record
ord-3de0824770034b6b8b9bc5851d7b93a0
Source dataset
uspto-grants-1993_02
Patent number
US05189053

Reaction notes

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