4,4'-Diaminodiphenyl Ether → HCID 67875422, compound

HRID 2082417Notes

Reaction equation

HRID 2082417 reaction equation
[O:1]([C:9]1C=C[C:12]([NH2:13])=[CH:11][CH:10]=1)[C:2]1C=CC(N)=C[CH:3]=1.C1(=O)OC(=[O:20])C=C1.C1C(C(C2C=CC3C(OC(=O)C=3C=2)=O)=O)=CC2C(OC(=O)C=2C=1)=O>CC(N(C)C)=O>[C:12]1(=[O:20])[NH:13][C:9](=[O:1])[CH:10]=[CH:11]1.[CH:2]#[CH:3]

Participants

5

Reactant 3

HCID 75794,4'-Diaminodiphenyl EtherHCID 7923Maleic AnhydrideHCID 754984,4'-Carbonyldiphthalic anhydride

Product 1

HCID 67875422HCID 67875422, compound

Reagents, catalysts & solvents 1

HCID 31374DimethylacetamideSolvent2×

Procedure

A maleimide-acetylene terminated monomeric material was prepared. A solution of 0.05 moles (200.242 g/mol) 4,4'-oxydianiline (ODA) and 0.05 moles (98.06 g/mol) maleic anhydride (MA) in 50 ml of DMAc was combined with a solution of 0.05 moles (322.234 g/mol) benzophenonetetracarboxylic dianhydride (BTDA) and 0.05 moles (117.1512 g/mol) APA in 50 ml DMAc. The solutions were blended, cyclized, filtered, and dried as in Example 1. The resulting monomeric material had the following primary structure: ##STR5##

Workup

  1. filtrationfiltered
  2. customdried as in Example 1

Sources & evidence

ORD record
ord-ad20f2adba3d4a548eaeaa77c917fc3d
Source dataset
uspto-grants-1993_02
Patent number
US05189129

Reaction notes

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