Methyl iodide → HCID 20360738, compound

HRID 2082834Notes

Reaction equation

HRID 2082834 reaction equation
[C:1]([O:4][C:5]1[C:6]([OH:19])=[C:7]([CH:16]=[CH:17][CH:18]=1)[C:8]([CH2:10][CH2:11][C:12]([O:14][CH3:15])=[O:13])=[O:9])(=[O:3])[CH3:2].[C:20](=O)([O-])[O-].[K+].[K+].CI>CC(C)=O>[C:1]([O:4][C:5]1[C:6]([O:19][CH3:20])=[C:7]([CH:16]=[CH:17][CH:18]=1)[C:8]([CH2:10][CH2:11][C:12]([O:14][CH3:15])=[O:13])=[O:9])(=[O:3])[CH3:2]

Participants

5

Reactant 3

HCID 6328Methyl iodideHCID 11430Potassium CarbonateHCID 20360811HCID 20360811, compound

Product 1

HCID 20360738HCID 20360738, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

A stirred mixture of methyl 3-(3-acetoxy-2-hydroxybenzoyl)-propionate, potassium carbonate, methyl iodide, and dry acetone, was heated under reflux for 24 hours. Evaporation of the filtered solution gave methyl 3-(3-acetoxy-2-methoxybenzoyl)-propionate.

Workup

  1. temperaturewas heated
  2. temperatureunder reflux for 24 hours
  3. customEvaporation of the filtered solution

Sources & evidence

ORD record
ord-db32c2f8392442cb992280d6a1206498
Source dataset
uspto-grants-1978_04
Patent number
US04082843

Reaction notes

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