1-Dodecanol → HCID 178443312, compound

Participants

Reaction Conditions

Reaction Steps

In a 500 ml four-neck round-bottom flask, as described in Example 1, 148.85 g of tributyltin oxide and 110 g dimethyl phosphite are heated with stirring to about 120° C. The reaction mixture is kept at this temperature for about 2 hours, dimethyl ether being split off. The reaction mixture is then heated with stirring under a vacuum of 20 to 5 mm Hg at 145° C, until the excess dimethyl phosphite has been distilled off. 193.3 g of tributyltin methyl phosphite are obtained. 128.5 g of tributyltin methyl phosphite and 68.7 g of lauryl alcohol are heated with stirring in a 500 ml four-neck round-bottom flask equipped with a stirrer, thermometer, standard taper glass stopper, stillhead with condenser, cooled distillate receiver and cold trap at 140° C for 5 hours, for one hour of which a vacuum (30 - 5 mm HG) is applied. Methanol is distilled off. 178 g tributyltin lauryl phosphite are obtained.

Provenance & Evidence