Benzoic anhydride → HCID 22023478, compound

HRID 2083199Notes

Reaction equation

HRID 2083199 reaction equation
[CH2:1]([Sn:5](=O)[CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[C:11]([O:19]C(=O)C1C=CC=CC=1)(=[O:18])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>>[C:11]([O-:19])(=[O:18])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.[CH2:1]([Sn+2:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:2][CH2:3][CH3:4].[C:11]([O-:19])(=[O:18])[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

Participants

3

Reactant 2

HCID 7167Benzoic anhydrideHCID 61221Dibutyltin oxide

Product 1

HCID 22023478HCID 22023478, compound

Procedure

A 49.74 g. (0.2 mole) portion of dibutyltin oxide and 22.62 g. (0.1 mole) of benzoic anhydride were intimately mixed in a Waring® Blender for 1 minute. A reaction initiated almost immediately, as demonstrated by infra-red spectroscopy. After standing at ambient temperature for about three weeks, the reaction appeared to be complete. Infra-red spectroscopic analysis of the product demonstrated that virtually all the original anhydride had been consumed, as demonstrated by the disappearance of absorption maxima at 5.6μ and 5.8μ. New absorption maxima at 6.3μ and 6.5μ are indicative of the presence of ##STR5## moieties. B. Dibutyltin Stearate

Workup

  1. waitAfter standing at ambient temperature for about three weeks
  2. customhad been consumed
  3. customas demonstrated by the disappearance of absorption maxima at 5.6μ and 5.8μ
  4. customNew absorption maxima at 6.3μ and 6.5μ

Sources & evidence

ORD record
ord-c1aa393bdee646c39532785c6263d9a4
Source dataset
uspto-grants-1978_04
Patent number
US04085077

Reaction notes

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