Hexamethylenediamine → HCID 21332441, compound

HRID 2083333Notes

Reaction equation

HRID 2083333 reaction equation
[CH2:1]1[O:13][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[NH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][NH2:21]>C(O)C>[CH2:20]([NH:21][CH2:1][CH:2]([OH:13])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][NH:14][CH2:1][CH:2]([OH:13])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 16402HexamethylenediamineHCID 178581,2-Epoxydodecane

Product 1

HCID 21332441HCID 21332441, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

In a manner similar to that of Example 1, condensation of 1-dodecene oxide (50 g.) and hexamethylenediamine (15.8 g.) and recrystallization of the resulting product from ethanol gave N,N'-(1,6-hexylene)-bis[2-hydroxydodecylamine] (I: R = CH3 (CH2)9, R' = H, X = (CH2)6, Z = H) (35 g., m.p. 123.6°-128.0° C.).

Sources & evidence

ORD record
ord-8e6639855a5f45b283f7c658b8170ae7
Source dataset
uspto-grants-1978_04
Patent number
US04085144

Reaction notes

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