Potassium Carbonate → HCID 60077951, compound

HRID 2085189Notes

Reaction equation

HRID 2085189 reaction equation
[CH3:1][C:2]1([CH3:17])[CH2:6][O:5][C:4]([C:7]2[O:11][C:10]3[CH:12]=[CH:13][CH:14]=[C:15]([OH:16])[C:9]=3[CH:8]=2)=[N:3]1.S(C1C=CC([N+]([O-])=O)=CC=1)(O[CH2:22][C@H:23]1[O:25][CH2:24]1)(=O)=O.C(=O)([O-])[O-].[K+].[K+]>>[CH2:22]([O:16][C:15]1[C:9]2[CH:8]=[C:7]([C:4]3[O:5][CH2:6][C:2]([CH3:17])([CH3:1])[N:3]=3)[O:11][C:10]=2[CH:12]=[CH:13][CH:14]=1)[C@H:23]1[O:25][CH2:24]1

Participants

4

Reactant 3

HCID 11430Potassium CarbonateHCID 10868995(S)-(+)-Glycidyl-4-nitrobenzoateHCID 135794300HCID 135794300, compound

Product 1

HCID 60077951HCID 60077951, compound

Procedure

By the reactions in the same manner as in Starting Material Synthesis Example 1 using 2-(4,4-dimethyloxazolin-2-yl)-4-hydroxybenzo(b)furan (1.50 g), (S)-glycidyl nosylate (1.68 g) and potassium carbonate (2.69 g), a crude product of the title compound was quantitatively obtained as a pale-yellow oil.

Sources & evidence

ORD record
ord-349ea7e9b32b48dfb72d359cf98287f9
Source dataset
uspto-grants-2004_04
Patent number
US06720320B2

Reaction notes

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