huagongshe.com
HRID2086332

反应详情

EQUATION

反应方程式

HRID 2086332 的结构方程式

REACTANTS

反应物

1
结构：[N-]=[N+]=NCCOCCOCCN=[N+]=[N-]
HCID10845705

Poly(oxy-1,2-ethanediyl), α-(2-azidoethyl)-ω-(2-azidoethoxy)-

C6H12N6O2

PRODUCTS

生成物

1
结构：NCCOCCOCCN
HCID70248

2,2'-[Ethane-1,2-diylbis(oxy)]diethanamine

C6H16N2O2

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pt]
催化剂HCID23939

Platinum

Pt

结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

To a solution of diazide 19 (14.67 g, 0.073 mol) in THF (100 ml) 1.5 g of 5% Pt on charcoal is added. The mixture is stirred for 12 h under hydrogen. Filtration through Celite™ and evaporation of solvents at reduced pressure gives 1,8-diamino-3,6-dioxa-octane 20.

WORKUP

后处理

  1. filtrationFiltration
  2. customthrough Celite™ and evaporation of solvents at reduced pressure