Sulfur → HCID 86647649, compound

HRID 2092689Notes

Reaction equation

HRID 2092689 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([O:10][S:11]([CH:14]2[CH2:16][CH2:15]2)(=[O:13])=[O:12])=[CH:6][CH:5]=1)([O-])=O.[P].[S]>[Pd].C(O)C.CCOC(C)=O>[NH2:1][C:4]1[CH:9]=[CH:8][C:7]([O:10][S:11]([CH:14]2[CH2:16][CH2:15]2)(=[O:13])=[O:12])=[CH:6][CH:5]=1

Participants

6

Reactant 3

HCID 5362487SulfurHCID 5462309PhosphorusHCID 86647650HCID 86647650, compound

Product 1

HCID 86647649HCID 86647649, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 21584252Ethanol ethylacetateSolvent

Procedure

This material was prepared from cyclopropanesulfonic acid 4-nitro-phenyl ester (J. F. King et al; Phosphorus, Sulfur and Silicon and the Related Elements; 1-4; 1993; p 445) (1.096 g) by hydrogenation over 10% Pd/C as catalyst, in ethanol/AcOEt as solvent (10 ml/15 ml) for 16 h, and at atmospheric pressure and RT. Yellow oil (0.55 g). MS (m/e): 214.2 [MH+].

Workup

  1. customat atmospheric pressure and RT

Sources & evidence

ORD record
ord-67fd364acd0c4753ae1393f33c673fed
Source dataset
uspto-grants-2013_05
Patent number
US08440710B2

Reaction notes

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