Sulfoxonium, trimethyl-, iodide (1:1) → HCID 58230017, compound

HRID 2092715Notes

Reaction equation

HRID 2092715 reaction equation
[F:1][C:2]([F:24])([F:23])[CH2:3][O:4][C:5]1[CH:10]=[CH:9][C:8]([N:11]2[CH2:15][CH2:14][C:13]3([CH2:20][CH2:19][C:18](=[O:21])[CH2:17][CH2:16]3)[C:12]2=[O:22])=[CH:7][CH:6]=1.[I-].[CH3:26][S+](C)(C)=O>>[F:24][C:2]([F:1])([F:23])[CH2:3][O:4][C:5]1[CH:10]=[CH:9][C:8]([N:11]2[CH2:15][CH2:14][C:13]3([CH2:16][CH2:17][C:18]4([O:21][CH2:26]4)[CH2:19][CH2:20]3)[C:12]2=[O:22])=[CH:7][CH:6]=1

Participants

3

Reactant 2

HCID 74498Sulfoxonium, trimethyl-, iodide (1:1)HCID 66579525HCID 66579525, compound

Product 1

HCID 58230017HCID 58230017, compound

Procedure

The title compound was prepared in analogy to example 346 step 1 from 2-[4.5]decane-1,8-dione (described in example 86 step 1) and trimethylsulfoxonium iodide. White solid (87%). MS (m/e): 356.1 [MH+].

Sources & evidence

ORD record
ord-a91d4f8375f24c179bbaa832effd9dd7
Source dataset
uspto-grants-2013_05
Patent number
US08440710B2

Reaction notes

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