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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2095221Generated: October 31, 2026

Benzaldehyde → N-(1,1-Dimethylethyl)benzenemethanamine

https://huagongshe.com/reaction/2095221

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzaldehydeHCID 240—
ReactantTert-ButylamineHCID 6385—
ReactantCyclohexanecarboxaldehydeHCID 16275—
ProductN-(1,1-Dimethylethyl)benzenemethanamineHCID 76908—
ProductN-(Cyclohexylmethyl)-2-methylpropan-2-amineHCID 11469319—

Reaction Steps

In an analogous manner to that in example 1c, except using 4.0% by weight of hydrogenation catalyst, based on the total amount of amine, 1 mol of tert-butylamine was reacted with cyclohexanal (example 3a) or benzaldehyde (example 3b) to give the corresponding secondary amines (tert-butylcyclohexylmethylamine and benzyl-tert-butylamine respectively) which were then analyzed by gas chromatography. For these reactions, yields of 87.3 area % (example 3a) and 14.2 area % (example 3b) of the corresponding secondary amines were achieved.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS08445726B2
Source datasetuspto-grants-2013_05
ORD IDord-e72215c3b0a1435aa742430b90c905b2
Source noteuspto-grants-2013_05