m-Chloroperbenzoic acid → N-{5-chloro-2-[(trifluoromethyl)sulfinyl]phenyl}-1-benzofuran-2-sulfonamide

HRID 2097754Notes

Reaction equation

HRID 2097754 reaction equation
C1C=C(Cl)C=C(C(OO)=[O:9])C=1.[Cl:12][C:13]1[CH:14]=[CH:15][C:16]([S:32][C:33]([F:36])([F:35])[F:34])=[C:17]([NH:19][S:20]([C:23]2[O:24][C:25]3[CH:31]=[CH:30][CH:29]=[CH:28][C:26]=3[CH:27]=2)(=[O:22])=[O:21])[CH:18]=1>C(Cl)Cl>[Cl:12][C:13]1[CH:14]=[CH:15][C:16]([S:32]([C:33]([F:35])([F:34])[F:36])=[O:9])=[C:17]([NH:19][S:20]([C:23]2[O:24][C:25]3[CH:31]=[CH:30][CH:29]=[CH:28][C:26]=3[CH:27]=2)(=[O:21])=[O:22])[CH:18]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 67972800HCID 67972800, compound

Product 1

HCID 67972481N-{5-chloro-2-[(trifluoromethyl)sulfinyl]phenyl}-1-benzofuran-2-sulfonamide

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Following General Procedure D using 10 equivalents of mCPBA in refluxing CH2Cl2, the title compound was prepared from N-{5-chloro-2-[(trifluoromethyl)thio]phenyl}-1-benzofuran-2-sulfonamide.

Sources & evidence

ORD record
ord-10b297fc400f4ca89d5f5d3c9ce863c5
Source dataset
uspto-grants-2013_05
Patent number
US08450367B2

Reaction notes

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