Toluene → 1-Methyl-6-(1-phenylsulfanyl-cyclopropoxy)-3,4-dihydro-1H-quinolin-2-one

HRID 209843Notes

Reaction equation

HRID 209843 reaction equation
[Ag+2:36].[C:32](=[O:33])([O-:34])[O-:35].[C:43]([O:44][CH2:45][CH3:46])(=[O:47])[CH3:48].[CH3:1][c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1.[CH3:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42].[I:8][C:9]1([S:12][c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[CH2:10][CH2:11]1.[OH:19][c:20]1[cH:21][c:22]2[c:27]([cH:28][cH:29]1)[N:26]([CH3:30])[C:25](=[O:31])[CH2:24][CH2:23]2>>[C:9]1([S:12][c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)([O:19][c:20]2[cH:21][c:22]3[c:27]([cH:28][cH:29]2)[N:26]([CH3:30])[C:25](=[O:31])[CH2:24][CH2:23]3)[CH2:10][CH2:11]1

Participants

8

Reactant 7

HCID 1140TolueneHCID 8058HexaneHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 11000298(1-Iodocyclopropyl)(phenyl)sulfaneHCID 219318286-Hydroxy-1-methyl-3,4-dihydroquinolin-2(1H)-oneHCID 178419107HCID 178419107, compound

Product 1

HCID 219318121-Methyl-6-(1-phenylsulfanyl-cyclopropoxy)-3,4-dihydro-1H-quinolin-2-one

Sources & evidence

ORD record
ord-82fba439c86646a09eb719fedf890bd6
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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