Water → HCID 86608401, compound

HRID 2099033Notes

Reaction equation

HRID 2099033 reaction equation
[C:1]1([S:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[S:9]([O:14]C)([O:12][CH3:13])(=[O:11])=[O:10].O>C(OCC)C>[S:9]([O-:14])([OH:12])(=[O:11])=[O:10].[CH3:8][S+:7]([CH3:13])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

5

Reactant 3

HCID 962WaterHCID 6497Dimethyl SulfateHCID 7520Thioanisole

Product 1

HCID 86608401HCID 86608401, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

6.2 g (0.05 mole) of thioanisole and 6.9 g (0.055 mole) of dimethyl sulfate were stirred for 12 hours at room temperature. 100 g of water and 50 ml of diethyl ether were added to the reaction solution whereupon the mixture separated into two layers. The aqueous layer was taken out, which was an aqueous solution of the target compound, dimethylphenylsulfonium hydrogen sulfate.

Workup

  1. customseparated into two layers

Sources & evidence

ORD record
ord-5eee64417b7c442984a2d0cacf77d722
Source dataset
uspto-grants-2009_08
Patent number
US07569326B2

Reaction notes

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