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HRID2099344

反应详情

EQUATION

反应方程式

HRID 2099344 的结构方程式

REACTANTS

反应物

2
结构：COCCN(CCOC)S(F)(F)F
HCID2734690

Sulfur, trifluoro[2-methoxy-N-(2-methoxyethyl)ethanaminato-.kappa.N]-, (T-4)-

C6H14F3NO2S

结构：CN1[C@@H]2CC=C[C@@]1(OC(=O)C(O)(c1ccccc1)c1ccccc1)CC2
HCID86585680

未命名化合物

PRODUCTS

生成物

1
结构：CN1[C@@H]2CC=C[C@@]1(O)CC2.O=C([O-])C(F)(c1ccccc1)c1ccccc1
HCID86585679

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClC(Cl)Cl
溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

15.86 mL (0.086 mol) of bis-(2-methoxyethyl)aminosulfur trifluoride is reacted with 25 g (0.072 mol) of 5f analogously to Example 4, step 4.3 in 480 mL of chloroform. The product is recrystallized from acetone in the form of its hydrochloride. Yield: 18.6 g of white crystals (67% of theory); melting point: 181° C.-182° C.

WORKUP

后处理

  1. customThe product is recrystallized from acetone in the form of its hydrochloride