Butyl nitrite → 5-Benzyloxy-6-methoxy-indan-1,2-dione 2-oxime

HRID 2101083Notes

Reaction equation

HRID 2101083 reaction equation
[CH2:1]([O:8][C:9]1[CH:10]=[C:11]2[C:15](=[CH:16][C:17]=1[O:18][CH3:19])[C:14](=[O:20])[CH2:13][CH2:12]2)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O:25][N:26]=O)CCC>>[CH2:1]([O:8][C:9]1[CH:10]=[C:11]2[C:15](=[CH:16][C:17]=1[O:18][CH3:19])[C:14](=[O:20])[C:13](=[N:26][OH:25])[CH2:12]2)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 10996Butyl nitriteHCID 147633965-Benzyloxy-6-methoxy-1-indanone

Product 1

HCID 766087855-Benzyloxy-6-methoxy-indan-1,2-dione 2-oxime

Procedure

Similar procedure as described in example 2a was used, starting from 5-Benzyloxy-6-methoxy-indan-1-one and n-butylnitrite to give 5-Benzyloxy-6-methoxy-indan-1,2-dione 2-oxime. LC-MS: m/e 298 (MH+).

Sources & evidence

ORD record
ord-fc487addd7a24ef9b4b63fd9f71b36c6
Source dataset
uspto-grants-2009_08
Patent number
US07572809B2

Reaction notes

Loading…