Butyl nitrite → 6-Bromo-indan-1,2-dione 2-oxime

HRID 2101166Notes

Reaction equation

[Br:1][C:2]1[CH:10]=[C:9]2[C:5]([CH2:6][CH2:7][C:8]2=[O:11])=[CH:4][CH:3]=1.C([O:16][N:17]=O)CCC>>[Br:1][C:2]1[CH:10]=[C:9]2[C:5]([CH2:6][C:7](=[N:17][OH:16])[C:8]2=[O:11])=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 10996Butyl nitrite

HCID 1397781-Indanone, 6-bromo-

Product 1

HCID 766087436-Bromo-indan-1,2-dione 2-oxime

Procedure

Similar procedure as described in example 9B was used, starting from 6-Bromo-indan-1-one and n-butylnitrite to give 6-Bromo-indan-1,2-dione 2-oxime. LC-MS: m/e 240 (MH+).

Sources & evidence

ORD record: ord-cbb187c86be34bbfb4ce3e90bb5c9f60
Source dataset: uspto-grants-2009_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07572809B2

Reaction notes

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