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HRID2104226

反应详情

EQUATION

反应方程式

HRID 2104226 的结构方程式

REACTANTS

反应物

2
结构：C[C@@H]1OC(=O)C(OC(=O)c2ccccc2)=C[C@H]1OC(=O)c1ccccc1
HCID11221893

未命名化合物

结构：[H][H]
HCID178418361

未命名化合物

PRODUCTS

生成物

1
结构：C[C@@H]1OC(=O)[C@H](OC(=O)c2ccccc2)C[C@H]1OC(=O)c1ccccc1
HCID11473679

未命名化合物

收率 85%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：CCOC(C)=O
溶剂HCID8857

Ethyl acetate

C4H8O2

PROCEDURE

实验过程

The compound (VIII) (6.1 g, 17.31 mmol) is dissolved in EtOAc (300 ml) and then 10%-Pd/C (400 mg) is added and is stirred for 3 hours at a room temperature after being substituted with hydrogen gas. The reactant is filtered by using celite 545. The solution is vacuum concentrated and then the compound (IX) (5.2 g, 85%) is isolated using flash column chromatography (toluene/EtOAc, 10:1, v/v).

WORKUP

后处理

  1. filtrationThe reactant is filtered
  2. concentrationconcentrated