HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 15016253, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Ethyl 2-bromopropionate | HCID 79040 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | HCID 178426256 | HCID 178426256 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | HCID 15016253 | HCID 15016253 | 28.7% |
Reaction Steps
The process was carried out as described in Example 8, starting with 1.1 g of sodium, 20 ml of methanol, 150 ml of dimethylsulfoxide, 8.5 g of 3-hydroxy-1-(4-methylphenyl)-1,2,4-1H-triazole and 8.7 g of ethyl 2-bromopropionate. A yield of 3.8 g of the desired product, m.p. 69°-71°, was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04931083 |
| Source dataset | uspto-grants-1990_06 |
| ORD ID | ord-0d88956555c6460986db142a54cc4a8e |
| Source note | uspto-grants-1990_06 |