HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromotoluene → HCID 23048955, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Bromotoluene | HCID 7236 | — |
| Reactant | 3-Methyl-2-thiophenecarboxaldehyde | HCID 79911 | — |
| Reactant | Magnesium | HCID 5462224 | — |
| Reactant | Tetrahydrofuran heptane | HCID 21263495 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 23048955 | HCID 23048955 | — |
Reaction Steps
The title compound was prepared from 2-bromotoluene (35.55 g, 0.208 mole), magnesium turnings (5.1 g, 0.208 mole) and 3-methylthiophene-2-aldehyde (23.6 g, 0.187 mole) by the method described in Example 6, using diethyl ether (150 ml) as solvent. The yield was 36.0 g (88%). T.l.c. rf=0.39 (SiO2, heptane/THF (7:3)).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04931450 |
| Source dataset | uspto-grants-1990_06 |
| ORD ID | ord-38c77cf9ce8844d09bfe2f791be12e00 |
| Source note | uspto-grants-1990_06 |