Hydrogen Bromide → HCID 23047537, compound

HRID 2107072Notes

Reaction equation

HRID 2107072 reaction equation
[C:1]([O-:6])(=[O:5])[C:2]([O-:4])=[O:3].[CH3:7][NH+:8]1[CH:13]([CH3:14])[CH2:12][CH:11]=[C:10]([C:15]([O:17]CC)=O)[CH2:9]1.[CH3:20][NH+:21]1[CH:26]([CH3:27])[CH2:25][CH:24]=[C:23]([C:28]([O:30]CC)=O)[CH2:22]1.[C:33](=[N:36]O)([NH2:35])[CH3:34].Br.[CH:39]([C:42](=[N:44]O)[NH2:43])(C)C>>[C:1]([O-:6])(=[O:5])[C:2]([O-:4])=[O:3].[CH3:7][NH+:8]1[CH:13]([CH3:14])[CH2:12][CH:11]=[C:10]([C:15]2[O:17][N:36]=[C:33]([CH3:34])[N:35]=2)[CH2:9]1.[CH3:20][NH+:21]1[CH:26]([CH3:27])[CH2:25][CH:24]=[C:23]([C:28]2[O:30][N:44]=[C:42]([CH3:39])[N:43]=2)[CH2:22]1

Participants

5

Reactant 4

HCID 260Hydrogen BromideHCID 30926N-HydroxyacetamidineHCID 2794833N'-Hydroxy-2-methylpropanimidamideHCID 86743105HCID 86743105, compound

Product 1

HCID 23047537HCID 23047537, compound

Procedure

The compound was synthesized as described in Example 17 using 1,6-dimethyl-3-ethoxycarbonyl-1,2,5,6-tetrahydropyridinium oxalate (Bishop, Z. Naturforsch. 25b, 1249-1251 (1970)) and acetamide oxime instead of arecoline, HBr and isopropylcarboxamide oxime, respectively. M.P. 115°-117° C.

Workup

  1. customThe compound was synthesized

Sources & evidence

ORD record
ord-6149aa3217ac40dda35e7fc8ddc9f1cd
Source dataset
uspto-grants-1990_06
Patent number
US04933353

Reaction notes

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