Ethyl Acetate → HCID 14567856, compound

HRID 2107144Notes

Reaction equation

HRID 2107144 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([CH:11]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[C:12]([OH:14])=[O:13])(=[O:10])=[O:9])=[CH:4][CH:3]=1.[OH-].[K+].[CH2:23](OC(=O)C)[CH3:24]>>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([CH:11]([CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[C:12]([O:14][CH2:23][CH3:24])=[O:13])(=[O:9])=[O:10])=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 8857Ethyl AcetateHCID 14797Potassium HydroxideHCID 23047848HCID 23047848, compound

Product 1

HCID 14567856HCID 14567856, compound

Procedure

By the procedure described in Example 1(b), 2.6 g (60% of theory) of 2-[(4-methylphenyl)sulfonyl]octanoic acid, MP 111°-123° C. (acetic acid ethyl ester), is obtained from 4.75 g (14.5 mmol) of ethyl 2-[(4-methylphenyl)sulfonyl]octanoate (Example 13) and 32 ml of 1N potash lye.

Sources & evidence

ORD record
ord-1c70accf6ed440bb90bb65b50f5d9eb9
Source dataset
uspto-grants-1990_06
Patent number
US04933367

Reaction notes

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