Glycidol → HCID 13725511, compound

HRID 2107539Notes

Reaction equation

HRID 2107539 reaction equation
[CH2:1]1[O:3][CH:2]1[CH2:4][OH:5].[C:6]([N:11]=[C:12]=[O:13])(=[O:10])[C:7]([CH3:9])=[CH2:8]>C(Cl)(Cl)Cl.ClCCCl>[C:6]([NH:11][C:12](=[O:13])[O:5][CH2:4][CH:2]1[O:3][CH2:1]1)(=[O:10])[C:7]([CH3:9])=[CH2:8]

Participants

5

Reactant 2

HCID 11164GlycidolHCID 10942374Methacryloyl isocyanate

Product 1

HCID 13725511HCID 13725511, compoundYield 99.9%

Reagents, catalysts & solvents 2

HCID 111,2-DichloroethaneSolvent2×HCID 6212ChloroformSolvent2×

Procedure

Glycidol (2.13 g; 28.8 mmol) was dissolved in dry chloroform (20 ml) under ice-cooling, and a solution of methacryloyl isocyanate (3.2 g; 28.8 mmol) in 1,2-dichloroethane (20 ml) was dropwise added thereto under nitrogen stream. After completion of the addition, chloroform and 1,2-dichloroethane were evaporated under reduced pressure to give glycidyl N-methacryloylcarbamate (5.33 g) as a viscous, colorless oil. Viscosity, 3260 cp.

Workup

  1. temperaturecooling
  2. customwere evaporated under reduced pressure

Sources & evidence

ORD record
ord-2db8938275824732a9f00986ff5ef257
Source dataset
uspto-grants-1990_06
Patent number
US04935413

Reaction notes

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