1,2-Dichloroethane → HCID 54156050, compound

HRID 2107543Notes

Reaction equation

HRID 2107543 reaction equation
C([SH:3])C.[C:4]([N:9]=[C:10]=[O:11])(=[O:8])[C:5]([CH3:7])=[CH2:6].Cl[CH2:13][CH2:14]Cl>>[C:4]([NH:9][C:10](=[S:3])[O:11][CH2:13][CH3:14])(=[O:8])[C:5]([CH3:7])=[CH2:6]

Participants

4

Reactant 3

HCID 111,2-Dichloroethane2×HCID 6343EthanethiolHCID 10942374Methacryloyl isocyanate

Product 1

HCID 54156050HCID 54156050, compound

Procedure

A solution of ethanethiol (1.24 g; 20 mmol) in 1,2-dichloroethane (12 ml) was dropwise added to a solution of methacryloyl isocyanate (2.22 g; 20 mmol) in 1,2-dichloroethane (14 ml) in 10 minutes under nitrogen stream while cooling with ice. After completion of the addition, the reaction mixture was stirred for 30 minutes. The solvent was removed by evaporation under reduced pressure to give ethyl N-methacryloylthiocarbamate (2.17 g) as a pale yellow liquid. Viscosity, 150 cp.

Workup

  1. temperaturewhile cooling with ice
  2. additionAfter completion of the addition
  3. customThe solvent was removed by evaporation under reduced pressure

Sources & evidence

ORD record
ord-3d9ae3929e944e27bb8ea6698a02b651
Source dataset
uspto-grants-1990_06
Patent number
US04935413

Reaction notes

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