m-Chloroperbenzoic acid → HCID 23046390, compound

HRID 2107734Notes

Reaction equation

HRID 2107734 reaction equation
[CH3:1][S:2]([C:4]1[NH:5][CH:6]=[C:7]([C:9](=[O:26])[CH2:10][C:11]2[CH:16]=[C:15]([C:17]([CH3:20])([CH3:19])[CH3:18])[C:14]([OH:21])=[C:13]([C:22]([CH3:25])([CH3:24])[CH3:23])[CH:12]=2)[CH:8]=1)=[O:3].ClC1C=CC=C(C(OO)=[O:35])C=1>>[CH3:1][S:2]([C:4]1[NH:5][CH:6]=[C:7]([C:9](=[O:26])[CH2:10][C:11]2[CH:16]=[C:15]([C:17]([CH3:18])([CH3:19])[CH3:20])[C:14]([OH:21])=[C:13]([C:22]([CH3:25])([CH3:24])[CH3:23])[CH:12]=2)[CH:8]=1)(=[O:35])=[O:3]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 23046313HCID 23046313, compound

Product 1

HCID 23046390HCID 23046390, compound

Procedure

For example, using 2-methylsulfinyl-4-[2-(3,5-di-t-butyl-4-hydroxyphenyl)-1-oxo-ethyl]pyrrole in this general reaction together with one molar equivalent of m-chloroperbenzoic acid yields 2-methylsulfonyl-4-[2-(3,5-di-t-butyl-4-hydroxyphenyl)-1-oxo-ethyl]pyrrole (a compound according to Formula X wherein: m is 1; n is 1; R is H; and X is SO2CH3 ; and Y and Z are each H).

Sources & evidence

ORD record
ord-81833a318f444b69a72894e967d4a52e
Source dataset
uspto-grants-1990_06
Patent number
US04935440

Reaction notes

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