Iodoethane → HCID 14852422, compound

HRID 2107744Notes

Reaction equation

[S:1]([C:4]1[NH:5][CH:6]=[C:7]([C:9](=[O:25])[C:10]2[CH:15]=[C:14]([C:16]([CH3:19])([CH3:18])[CH3:17])[C:13]([OH:20])=[C:12]([C:21]([CH3:24])([CH3:23])[CH3:22])[CH:11]=2)[CH:8]=1)[C:2]#N.[CH2:26](I)C>>[CH3:26][N:5]1[CH:6]=[C:7]([C:9](=[O:25])[C:10]2[CH:11]=[C:12]([C:21]([CH3:22])([CH3:24])[CH3:23])[C:13]([OH:20])=[C:14]([C:16]([CH3:17])([CH3:18])[CH3:19])[CH:15]=2)[CH:8]=[C:4]1[S:1][CH3:2]

Participants

Reactant 2

HCID 6340Iodoethane

HCID 14852427HCID 14852427, compound

Product 1

HCID 14852422HCID 14852422, compound

Procedure

Similarly, by following the procedure of part A above and substituting N-methyl-2-thiocyano-4-(3,5-di-t-butyl-4-hydroxybenzoyl)pyrrole for 2-thiocyano-4-(3,5-di-t-butyl-4-hydroxybenzoyl)pyrrole, and substituting methyl iodide for ethyl iodide, there is obtained N-methyl-2-methylthio-4-(3,5-di-t-butyl-4-hydroxybenzoyl)pyrrole [mp 173°-175° C.; 1H nmr: 1.50s (18H), 2.3s (3H), 3.73s (3H), 5.6s (OH), 6.81m (1H), 7.38m (1H), 7.76s (2H)].

Sources & evidence

ORD record: ord-d986543257824197b281f668a1f9ab2d
Source dataset: uspto-grants-1990_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04935440

Reaction notes

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