4-(2,2-Dimethylpropyl)-2-(prop-2-en-1-yl)phenol → 4-(2,2-Dimethylpropyl)-2-propylphenol

HRID 2113146Notes

Reaction equation

HRID 2113146 reaction equation
[CH2:1]([C:4]1[CH:9]=[C:8]([CH2:10][C:11]([CH3:14])([CH3:13])[CH3:12])[CH:7]=[CH:6][C:5]=1[OH:15])[CH:2]=[CH2:3]>[Pd].C(OCC)(=O)C>[CH3:12][C:11]([CH3:13])([CH3:14])[CH2:10][C:8]1[CH:7]=[CH:6][C:5]([OH:15])=[C:4]([CH2:1][CH2:2][CH3:3])[CH:9]=1

Participants

4

Reactant 1

HCID 690541424-(2,2-Dimethylpropyl)-2-(prop-2-en-1-yl)phenol

Product 1

HCID 576434324-(2,2-Dimethylpropyl)-2-propylphenol

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8857Ethyl AcetateSolvent

Procedure

A mixture of 2-allyl-4-(2,2-dimethyl-propyl)phenol (0.70 g, 3.4 mmol) and 10% palladium on carbon (0.14 g) in ethyl acetate was stirried under hydrogen (1 atm) for 1 h. The reaction mixture was filtered and the filtrate was concentrated to give the title compound.

Workup

  1. filtrationThe reaction mixture was filtered
  2. concentrationthe filtrate was concentrated

Sources & evidence

ORD record
ord-7745f317d018492c91177168eab1c9e3
Source dataset
uspto-grants-2009_04
Patent number
US07524882B2

Reaction notes

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