Oxygen → Potassium Persulfate

HRID 2117238Notes

Reaction equation

HRID 2117238 reaction equation
[OH:1][O:2][S:3]([O-:5])=[O:4].[K+:6].[O:7]=O.[OH:9][S:10]([O-])(=[O:12])=[O:11].[K+]>O>[S:3]([O:2][O:1][S:10]([O-:12])(=[O:11])=[O:9])([O-:7])(=[O:5])=[O:4].[K+:6].[K+:6]

Participants

5

Procedure

Comparative Example A was prepared as for the “Conventional Complete Solution” described in Table 2 of Example 1 of U.S. Pat. No. 6,818,142. A 11.2% potassium monopersulfate solution was prepared by dissolving OXONE (12.6 g) potassium monopersulfate in deionized water (100 g) at a temperature of 22° C. The OXONE was mixed until completely dissolved. The resulting solution produced was prepared below the saturation limit expressed in Table 1 above. The resulting solution contained 0.51% active oxygen, 5.00% KHSO5, 2.54% KHSO4, pH=1.2, 10.56% total dissolved solids (TDS), and a 0.15:1 weight ratio of AO/SO4. A rate constant was derived from the data in Table 2 of U.S. Pat. No. 6,818,142 and found to be k=0.0062. Using Equation 1 above, the value of t10% was 17 days, where t10% is the time it takes to loose 10% of the active oxygen.

Workup

  1. customComparative Example A was prepared as for the “Conventional Complete Solution”
  2. dissolutionuntil completely dissolved
  3. customThe resulting solution produced
  4. customwas prepared below the saturation limit
  5. dissolutiondissolved solids (TDS)

Sources & evidence

ORD record
ord-331a9e3a2189445daaa1457b93d2cfdd
Source dataset
uspto-grants-2008_10
Patent number
US07442323B2

Reaction notes

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