Benzenamine, 3,5-bis(trifluoromethyl)- → HCID 59816222, compound

HRID 2118151Notes

Reaction equation

HRID 2118151 reaction equation
[F:1][C:2]([F:15])([F:14])[C:3]1[CH:4]=[C:5]([CH:7]=[C:8]([C:10]([F:13])([F:12])[F:11])[CH:9]=1)[NH2:6].[CH2:16]1[C:29]2[C:20](=[N:21][C:22]3[C:23](=O)[CH2:24][CH2:25][CH2:26][C:27]=3[CH:28]=2)[C:19](=O)[CH2:18][CH2:17]1>>[F:1][C:2]([F:14])([F:15])[C:3]1[CH:4]=[C:5]([N:6]=[C:19]2[C:20]3[C:29](=[CH:28][C:27]4[CH2:26][CH2:25][CH2:24][C:23](=[N:6][C:5]5[CH:7]=[C:8]([C:10]([F:11])([F:12])[F:13])[CH:9]=[C:3]([C:2]([F:1])([F:14])[F:15])[CH:4]=5)[C:22]=4[N:21]=3)[CH2:16][CH2:17][CH2:18]2)[CH:7]=[C:8]([C:10]([F:11])([F:12])[F:13])[CH:9]=1

Participants

3

Reactant 2

HCID 9480Benzenamine, 3,5-bis(trifluoromethyl)-HCID 355603HCID 355603, compound

Product 1

HCID 59816222HCID 59816222, compound

Procedure

was synthesized by methods similar to those in Examples 3 and 4: 3,5-bis-trifluoromethylaniline was condensed with 2,3,7,8-tetrahydro-1H,6H-acridine-4,5-dione to yield 4,5-bis[3,5-bis-trifluoromethylphenylimino]-1,2,3,4,5,6,7,8-octahydroacridine (5). The complexation of (5) with FeCl2.4H2O was carried out with azeotropic removal of methanol in benzene. The structure of the final complex was proved by direct probe GC. Exact mass direct probe calculated for C29H19Cl2F12FeN3: 763.01. Found: 763.01.

Workup

  1. customwas synthesized by methods similar to those in Examples 3 and 4

Sources & evidence

ORD record
ord-bdf394e0dd9e4f8f93aa15249bf2aabd
Source dataset
uspto-grants-2008_10
Patent number
US07442819B2

Reaction notes

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