Benzylamine → HCID 51056108, compound

HRID 2118698Notes

Reaction equation

HRID 2118698 reaction equation
O=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[CH2:13]([NH2:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C(O)C>[CH2:13]([NH:20][C@@H:2]1[O:10][C@H:9]([CH2:11][OH:12])[C@@H:7]([OH:8])[C@H:5]([OH:6])[C@H:3]1[OH:4])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Participants

4

Reactant 2

HCID 7504BenzylamineHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

Product 1

HCID 51056108HCID 51056108, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

50 g of D-glucose are dissolved in 1,000 ml of hot ethanol and, after addition of 89 g of benzylamine, left at room temperature for 48 hours. The mixture is then cooled in ice and the product is precipitated with petroleum ether. It is filtered off with suction, washed with ether and dried in vacuo.

Workup

  1. temperatureThe mixture is then cooled in ice
  2. customthe product is precipitated with petroleum ether
  3. filtrationIt is filtered off with suction
  4. washwashed with ether
  5. customdried in vacuo

Sources & evidence

ORD record
ord-4265a3d253b34f0aae9d800a79b192d2
Source dataset
uspto-grants-1987_07
Patent number
US04680287

Reaction notes

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