HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 15930829, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Morpholine | HCID 8083 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Product | 2-Morpholinoethanol | HCID 61163 | — |
| Product | HCID 15930829 | HCID 15930829 | 87% |
Reaction Steps
The procedure of Example 1 was repeated using a catalyst system consisting of 39 mg RuCl3 ×H2O (43.1% Ru, 1.7×10-4 mol Ru) and 226 mg PPh3 (8.6×10-4 mol). In this run, the maximum reaction pressure was 71 psig which, on cooling to room temperature. dropped to 27 psig. Analysis of reaction products showed 100% conversion of morpholine with yields of hydroxyethylmorpholine and bismorpholinoethane being 87% and 7%, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04680393 |
| Source dataset | uspto-grants-1987_07 |
| ORD ID | ord-1185526a2fc24c4f8bbbee68797b3472 |
| Source note | uspto-grants-1987_07 |