Benzylamine → HCID 51056108, compound

HRID 2119144Notes

Reaction equation

HRID 2119144 reaction equation
O=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[CH2:13]([NH2:20])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C(O)C>[CH2:13]([NH:20][C@@H:2]1[O:10][C@H:9]([CH2:11][OH:12])[C@@H:7]([OH:8])[C@H:5]([OH:6])[C@H:3]1[OH:4])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Participants

4

Reactant 2

HCID 7504BenzylamineHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

Product 1

HCID 51056108HCID 51056108, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

50 g of D-glucose were dissolved in 1,000 ml of hot ethanol and, after addition of 89 g of benzylamine, were left at room temperature for 48 hours. The mixture was then cooled with ice and the product was precipitated with petroleum ether. It was filtered off with suction, washed with ether and dried in vacuo.

Workup

  1. temperatureThe mixture was then cooled with ice
  2. customthe product was precipitated with petroleum ether
  3. filtrationIt was filtered off with suction
  4. washwashed with ether
  5. customdried in vacuo

Sources & evidence

ORD record
ord-a8cae76569174d2684fd8bb4507930e4
Source dataset
uspto-grants-1987_07
Patent number
US04683222

Reaction notes

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