2,6-Di-tert-butyl-4-methylphenol → Magnesium di(phenolate)

HRID 2119734Notes

Reaction equation

HRID 2119734 reaction equation
C([C:5]1[CH:10]=[C:9](C)[CH:8]=[C:7](C(C)(C)C)[C:6]=1[OH:16])(C)(C)C.C([Mg:21]CCCC)CCC>CCCCCCC.C1CCCCC1>[C:6]1([O-:16])[CH:7]=[CH:8][CH:9]=[CH:10][CH:5]=1.[Mg+2:21].[C:6]1([O-:16])[CH:7]=[CH:8][CH:9]=[CH:10][CH:5]=1

Participants

5

Reactant 2

HCID 314042,6-Di-tert-butyl-4-methylphenolHCID 178448196HCID 178448196, compound

Product 1

HCID 13616137Magnesium di(phenolate)

Reagents, catalysts & solvents 2

HCID 8078CyclohexaneSolventHCID 8900HeptaneSolvent

Procedure

0.637 g of 2,6-di-tert-butyl-4-methylphenol (from Aldrich) and 2.9 ml of a 1.0 molar solution of dibutylmagnesium (DBM) in heptane (from Aldrich) were combined at 25° C. and stirred for 10 hours in 26 ml of cyclohexane before use.

Workup

  1. customwere combined at 25° C.

Sources & evidence

ORD record
ord-7764d8546b2f43f0a50dc4efc0ff25fc
Source dataset
uspto-grants-2004_02
Patent number
US06686423B1

Reaction notes

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