Methyl p-toluenesulfonate → HCID 131724357, compound

HRID 2121927Notes

Reaction equation

HRID 2121927 reaction equation
[CH2:1]([N:8]1[C:12](=[O:13])[C:11](=[C:14]2[N:18]([CH3:19])[C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:16][S:15]2)[S:10][C:9]1=[S:26])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:27]1([CH3:38])[CH:32]=[CH:31][C:30]([S:33]([O:36]C)(=[O:35])=[O:34])=[CH:29][CH:28]=1>>[C:27]1([CH3:38])[CH:28]=[CH:29][C:30]([S:33]([O-:36])(=[O:34])=[O:35])=[CH:31][CH:32]=1.[CH2:1]([N+:8]1[C:12](=[O:13])[C:11](=[C:14]2[N:18]([CH3:19])[C:17]([C:20]3[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=3)=[CH:16][S:15]2)[S:10][C:9]=1[S:26][CH3:27])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 6645Methyl p-toluenesulfonateHCID 73690413HCID 73690413, compound

Product 1

HCID 131724357HCID 131724357, compound

Procedure

The title compound was prepared from 3′-benzyl-3-methyl-4-phenyl-2′-thioxo-2′,3′-dihydro-3H-[2,5′]bithiazolyliden-4′-one and methyl p-toluenesulfonate in a manner similar to that described in Example 1. 1H-NMR (CDCl3): δ 7.72 (2H, d), 7.49-7.56 (3H, m), 7.42-7.47 (2H, m), 7.36-7.41 (5H, m), 7.05 (2H, d), 6.99 (1H, s), 5.29 (2H, s), 4.26 (3H, s), 3.14 (3H, s), 2.29 (3H, s).

Sources & evidence

ORD record
ord-65306e83a26c46b7b47c8555445c81cd
Source dataset
uspto-grants-2004_02
Patent number
US06696473B2

Reaction notes

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