Bromide ion → Ethyl 1-formylcyclopropanecarboxylate

HRID 2130970Notes

Reaction equation

HRID 2130970 reaction equation
[Br-:28].[C:11](=[O:12])([O-:13])[OH:14].[CH2:1]([CH3:2])[O:3][C:4](=[O:5])[C:6]1([CH2:9][OH:10])[CH2:7][CH2:8]1.[CH3:16][C:17]1([CH3:26])[N:18]([O:19])[C:20]([CH3:21])([CH3:22])[CH2:23][CH2:24][CH2:25]1.[Cl:29][O-:30].[Cl:39][CH2:40][Cl:41].[Na+:15].[Na+:27].[Na+:31].[Na+:37].[Na+:38].[S:32]([O-:33])([O-:34])(=[O:35])=[S:36]>>[CH2:1]([CH3:2])[O:3][C:4](=[O:5])[C:6]1([CH:9]=[O:10])[CH2:7][CH2:8]1

Participants

9

Reactant 8

HCID 259Bromide ionHCID 769Bicarbonate IonHCID 923Sodium ion5×HCID 1084Thiosulfate ionHCID 6344DichloromethaneHCID 61739HypochloriteHCID 5499762,2,6,6-Tetramethylpiperidin-1-olHCID 12450336Ethyl 1-(hydroxymethyl)cyclopropane-1-carboxylate

Product 1

HCID 9964122Ethyl 1-formylcyclopropanecarboxylate

Sources & evidence

ORD record
ord-24b3e5f59de142d4bf2ce4fd7424eeed
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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