Sodium ion → ethyl 2-chloro-5-(4,5,6,7-tetrahydro-2-isopropoxy-4-oxo-3H-cyclopenta[d]pyrimidin-3-yl)-benzoate

HRID 2139707Notes

Reaction equation

HRID 2139707 reaction equation
[CH3:30][N:31]([CH3:32])[P:33](=[O:34])([N:35]([CH3:36])[CH3:37])[N:38]([CH3:39])[CH3:40].[CH:26]([CH3:27])([CH3:28])[Br:29].[Cl:1][c:2]1[c:3]([C:4](=[O:5])[O:6][CH2:7][CH3:8])[cH:9][c:10](-[n:13]2[c:14](=[O:23])[nH:15][c:16]3[c:17]([c:18]2=[O:19])[CH2:20][CH2:21][CH2:22]3)[cH:11][cH:12]1.[H-:24].[Na+:25]>>[Cl:1][c:2]1[c:3]([C:4](=[O:5])[O:6][CH2:7][CH3:8])[cH:9][c:10](-[n:13]2[c:14]([O:23][CH:26]([CH3:27])[CH3:28])[n:15][c:16]3[c:17]([c:18]2=[O:19])[CH2:20][CH2:21][CH2:22]3)[cH:11][cH:12]1

Participants

6

Reactant 5

HCID 923Sodium ionHCID 63582-BromopropaneHCID 12679HexamethylphosphoramideHCID 166653HydrideHCID 21270732ethyl 2-chloro-5-(1,2,4,5,6,7-hexahydro-2,4-dioxo-3H-cyclopenta[d]pyrimidin-3-yl)-benzoate

Product 1

HCID 21270718ethyl 2-chloro-5-(4,5,6,7-tetrahydro-2-isopropoxy-4-oxo-3H-cyclopenta[d]pyrimidin-3-yl)-benzoate

Sources & evidence

ORD record
ord-09404ea2c2cf4d2d8ca1a1a3b64b4db7
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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