Tetrahydrofuran → Ethyl 5-(3-acetyloxyphenylthio)-4-oxopentanoate

HRID 2140653Notes

Reaction equation

HRID 2140653 reaction equation
[Br:40][CH2:41][C:42]([CH2:43][CH2:44][C:45](=[O:46])[O:47][CH2:48][CH3:49])=[O:50].[C:19]([CH3:20])(=[O:21])[O:22][c:23]1[cH:24][c:25]([S:29][Si:30]([CH:31]([CH3:32])[CH3:33])([CH:34]([CH3:35])[CH3:36])[CH:37]([CH3:38])[CH3:39])[cH:26][cH:27][cH:28]1.[CH2:51]1[O:52][CH2:53][CH2:54][CH2:55]1.[CH3:2][CH2:3][CH2:4][CH2:5][N+:6]([CH2:7][CH2:8][CH2:9][CH3:10])([CH2:11][CH2:12][CH2:13][CH3:14])[CH2:15][CH2:16][CH2:17][CH3:18].[F-:1]>>[C:19]([CH3:20])(=[O:21])[O:22][c:23]1[cH:24][c:25]([S:29][CH2:41][C:42]([CH2:43][CH2:44][C:45](=[O:46])[O:47][CH2:48][CH3:49])=[O:50])[cH:26][cH:27][cH:28]1

Participants

6

Reactant 5

HCID 8028TetrahydrofuranHCID 16028TetrabutylammoniumHCID 28179Fluoride IonHCID 112210453-[1,1-bis (Methylethyl)-2-methyl-1-silapropylthio]phenyl acetateHCID 12397184Ethyl 5-bromo-4-oxopentanoate

Product 1

HCID 11426889Ethyl 5-(3-acetyloxyphenylthio)-4-oxopentanoate

Sources & evidence

ORD record
ord-edab4f0cf0f44f50a40015440c1e84f4
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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