Diethyl Ether → Methyl 7-bromo-5-methyl-2,3-dihydrobenzo[b]oxepine-4-carboxylate

HRID 2144145Notes

Reaction equation

HRID 2144145 reaction equation
[Br:3][c:4]1[cH:5][c:6]2[c:7]([cH:25][cH:26]1)[O:8][CH2:9][CH2:10][C:11]([C:21](=[O:22])[O:23][CH3:24])=[C:12]2[O:13][S:14]([C:15]([F:16])([F:17])[F:18])(=[O:19])=[O:20].[CH3:1][Li:2].[CH3:27][CH2:28][O:29][CH2:30][CH3:31].[Cu:32][I:33]>>[CH3:1][C:12]1=[C:11]([C:21](=[O:22])[O:23][CH3:24])[CH2:10][CH2:9][O:8][c:7]2[c:6]1[cH:5][c:4]([Br:3])[cH:26][cH:25]2

Participants

5

Reactant 4

HCID 3283Diethyl EtherHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 86685421Methyl 7-bromo-5-(((trifluoromethyl)sulfonyl)oxy)-2,3-dihydrobenzo[b]oxepine-4-carboxylateHCID 178418348HCID 178418348, compound

Product 1

HCID 71061088Methyl 7-bromo-5-methyl-2,3-dihydrobenzo[b]oxepine-4-carboxylate

Sources & evidence

ORD record
ord-20b7bc56f75547b8a646dafa27b5dffc
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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