Bromide ion → HCID 178481421, compound

HRID 2146452Notes

Reaction equation

HRID 2146452 reaction equation
[Br-:38].[CH2:19]([B:20]([CH2:21][CH3:28])[c:22]1[cH:23][n:24][cH:25][cH:26][cH:27]1)[CH3:29].[CH3:1][N:2]1[C:3](=[O:18])[CH2:4][CH2:5][C:6]2([CH3:17])[c:7]3[c:8]([cH:12][c:13]([Br:16])[cH:14][cH:15]3)[CH2:9][CH2:10][CH:11]12.[CH3:32][O:33][CH2:34][CH2:35][O:36][CH3:37].[CH3:39][CH2:40][CH2:41][CH2:42][N+:43]([CH2:44][CH2:45][CH2:46][CH3:47])([CH2:48][CH2:49][CH2:50][CH3:51])[CH2:52][CH2:53][CH2:54][CH3:55].[K+:31].[OH-:30].[OH2:56].[Pd:57].[c:115]1([P:116]([c:117]2[cH:118][cH:119][cH:120][cH:121][cH:122]2)[c:123]2[cH:124][cH:125][cH:126][cH:127][cH:128]2)[cH:129][cH:130][cH:131][cH:132][cH:133]1.[c:58]1([P:59]([c:60]2[cH:61][cH:62][cH:63][cH:64][cH:65]2)[c:66]2[cH:67][cH:68][cH:69][cH:70][cH:71]2)[cH:72][cH:73][cH:74][cH:75][cH:76]1.[c:77]1([P:78]([c:79]2[cH:80][cH:81][cH:82][cH:83][cH:84]2)[c:85]2[cH:86][cH:87][cH:88][cH:89][cH:90]2)[cH:91][cH:92][cH:93][cH:94][cH:95]1.[c:96]1([P:97]([c:98]2[cH:99][cH:100][cH:101][cH:102][cH:103]2)[c:104]2[cH:105][cH:106][cH:107][cH:108][cH:109]2)[cH:110][cH:111][cH:112][cH:113][cH:114]1>>[CH3:1][N:2]1[C:3](=[O:18])[CH2:4][CH2:5][C:6]2([CH3:17])[c:7]3[c:8]([cH:12][c:13](-[c:22]4[cH:23][n:24][cH:25][cH:26][cH:27]4)[cH:14][cH:15]3)[CH2:9][CH2:10][CH:11]12

Participants

11

Reactant 10

HCID 259Bromide ionHCID 813Potassium CationHCID 961HydroxideHCID 962WaterHCID 80711,2-DimethoxyethaneHCID 11776Triphenylphosphine4×HCID 16028TetrabutylammoniumHCID 23938PalladiumHCID 6428513-(Diethylboryl)pyridineHCID 221252194-Methyl-8-bromo-10b-methyl-1,2,3,4,4a, 5,6,10b-octahydrobenzo[f]quinolin-3-one

Product 1

HCID 178481421HCID 178481421, compound

Sources & evidence

ORD record
ord-383a289990064b26bfcfd1ecb5b2de78
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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