Acetate → (1S,2S)-ethyl 2-(4-bromophenyl)cyclopropanecarboxylate

HRID 2148572Notes

Reaction equation

HRID 2148572 reaction equation
[CH2:15]1[O:16][CH2:17][CH2:18][CH2:19]1.[CH2:1]([CH3:2])[O:3][C:4]([CH:5]=[CH:6][c:7]1[cH:8][cH:9][c:10]([Br:13])[cH:11][cH:12]1)=[O:14].[O-:21][C:22]([CH3:23])=[O:24].[O-:25][C:26]([CH3:27])=[O:28].[Pd+2:20]>>[CH2:1]([CH3:2])[O:3][C:4]([CH:5]1[CH:6]([c:7]2[cH:8][cH:9][c:10]([Br:13])[cH:11][cH:12]2)[CH2:15]1)=[O:14]

Participants

5

Reactant 4

HCID 175Acetate2×HCID 8028TetrahydrofuranHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 141107Ethyl 4-bromocinnamate

Product 1

HCID 23268273(1S,2S)-ethyl 2-(4-bromophenyl)cyclopropanecarboxylate

Sources & evidence

ORD record
ord-fb042e9a459744b6ae24500179988d29
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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