Chloride → 4,4-Dimethyl-6-bromo-2-oxo-thiochroman

HRID 215086Notes

Reaction equation

HRID 215086 reaction equation
[Al+3:2].[CH2:19]([Cl:20])[Cl:21].[CH3:5][C:6](=[CH:7][C:8](=[O:9])[S:10][c:11]1[cH:12][cH:13][c:14]([Br:17])[cH:15][cH:16]1)[CH3:18].[Cl-:1].[Cl-:3].[Cl-:4]>>[CH3:5][C:6]1([CH3:18])[CH2:7][C:8](=[O:9])[S:10][c:11]2[c:12]1[cH:13][c:14]([Br:17])[cH:15][cH:16]2

Participants

5

Reactant 4

HCID 312Chloride3×HCID 6344DichloromethaneHCID 104727Aluminum CationHCID 15661118S-(4-bromophenyl) 3,3-dimethylthioacrylate

Product 1

HCID 156611194,4-Dimethyl-6-bromo-2-oxo-thiochroman

Sources & evidence

ORD record
ord-1f62b6b880594d5bacceeeebbf07bf8d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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