Dimethylformamide → 3-Chloro-4-(1-methylcyclopropyl)-benzaldehyde

HRID 2157034Notes

Reaction equation

HRID 2157034 reaction equation
[Br:12][c:13]1[cH:14][c:15]([Cl:23])[c:16]([C:19]2([CH3:22])[CH2:20][CH2:21]2)[cH:17][cH:18]1.[CH3:24][CH2:25][CH2:26][CH2:27][Li:28].[CH:1]1([c:2]2[cH:3][cH:4][c:5]([CH:8]=[O:9])[cH:6][cH:7]2)[CH2:10][CH2:11]1.[O:29]=[CH:30][N:31]([CH3:32])[CH3:33]>>[CH:8](=[O:9])[c:13]1[cH:14][c:15]([Cl:23])[c:16]([C:19]2([CH3:22])[CH2:20][CH2:21]2)[cH:17][cH:18]1

Participants

5

Reactant 4

HCID 6228DimethylformamideHCID 115064744-CyclopropylbenzaldehydeHCID 693426514-Bromo-2-chloro-1-(1-methylcyclopropyl)benzeneHCID 178418339Butyllithium

Product 1

HCID 860938233-Chloro-4-(1-methylcyclopropyl)-benzaldehyde

Sources & evidence

ORD record
ord-07761688cb244d6d915347062d381284
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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